Search results for "chemistry [Arsenates]"
showing 10 items of 2372 documents
Heterogeneity of volatile sources along the Halmahera arc, Indonesia
2021
co-auteur étranger; International audience; The parallel Halmahera and Sangihe arcs in eastern Indonesia are sites of active arc-arc collision of considerable interest in developing understanding of the geodynamics and geochemistry of subduction zones. Owing to the comparative remoteness of the region, few ground-based studies of the volcanoes have been undertaken. Here, we report and integrate gas measurements and (isotope) geochemical analyses of lava samples for Dukono, Ibu, Gamkonora, Gamalama, and Makian volcanoes of the Halmahera arc. Summing gas fluxes for all five volcanoes indicates arcscale emission budgets for H 2 O, CO 2 , SO 2 , H 2 S, and H 2 of 96300±27000, 2093±450, 944±400,…
Passive vs. active degassing modes at an open-vent volcano (Stromboli, Italy)
2012
Abstract We report here on a UV-camera based field experiment performed on Stromboli volcano during 7 days in 2010 and 2011, aimed at obtaining the very first simultaneous assessment of all the different forms (passive and active) of SO 2 release from an open-vent volcano. Using the unprecedented spatial and temporal resolution of the UV camera, we obtained a 0.8 Hz record of the total SO 2 flux from Stromboli over a timeframe of ∼14 h, which ranged between 0.4 and 1.9 kg s −1 around a mean value of 0.7 kg s −1 and we concurrently derived SO 2 masses for more than 130 Strombolian explosions and 50 gas puffs. From this, we show erupted SO 2 masses have a variability of up to one order of mag…
Extensive magmatism and metamorphism at ca. 3.2 Ga in the eastern Kaapvaal Craton
2020
Abstract The timing of the emergence of modern-style plate tectonics on Earth is of fundamental importance in understanding the thermal and compositional history of the planet. Although the magmatism and metamorphism in the eastern Kaapvaal Craton was thought by some as geological records for mid-Archean subduction at 3.2 Ga, their petrogenesis was fiercely debated. To reveal the nature of the 3.2 Ga magmatism and metamorphism in the eastern Kaapvaal Craton, here we provide a comprehensive zircon and monazite U-Pb geochronological investigation, coupled with in situ trace element and Hf-O isotopic analyses, for the magmatic and metamorphic rocks from the Barberton granitoid-greenstone terra…
Dynamics of ice mass deformation: Linking processes to rheology, texture, and microstructure
2013
[1] Prediction of glacier and polar ice sheet dynamics is a major challenge, especially in view of changing climate. The flow behavior of an ice mass is fundamentally linked to processes at the grain and subgrain scale. However, our understanding of ice rheology and microstructure evolution based on conventional deformation experiments, where samples are analyzed before and after deformation, remains incomplete. To close this gap, we combine deformation experiments with in situ neutron diffraction textural and grain analysis that allows continuous monitoring of the evolution of rheology, texture, and microstructure. We prepared ice samples from deuterium water, as hydrogen in water ice has …
First simultaneous mercury and major volatiles characterization of atmospheric hydrothermal emissions at the Pisciarelli's fumarolic system (Campi Fl…
2020
Abstract Hydrothermal systems with active surface expressions are important natural source of atmospheric mercury. Here we report on the first simultaneous assessment of gaseous elemental mercury (GEM) and major volatiles (H2S and CO2) fluxes from the fumarolic system of Pisciarelli, currently the most active at the Campi Flegrei caldera (CFc), Naples (Italy). This was achieved via a GPS-synchronized Lumex and MultiGAS survey which extends similar investigations reported elsewhere. GEM concentrations measured in the fumarolic emissions were consistently above background air level close to the degassing area (mean ~ 8 ± 3 ng m−3 on average) and ranged up to 12,000 ng m−3. Our data evidenced …
Holocene surface ruptures of the Rurrand Fault, Germany—insights from palaeoseismology, remote sensing and shallow geophysics
2016
The Lower Rhine Embayment in Central Europe hosts a rift system that has very low deformation rates. The faults in this area have slip rates of less than 0.1 mm/yr, which does not allow to investigate ongoing tectonic deformation with geodetic techniques, unless they cover very long time spans. Instrumental seismicity does only cover a small fraction of the very long earthquake recurrence intervals of several thousands of years. Paleoseismological studies are needed to constrain slip rates and the earthquake history of such faults. Destructive earthquakes are rare in the study area, but did occur in historic times. In 1755/56, a series of strong earthquakes caused significant destruction in…
Late Paleozoic Ice Age glaciers shaped East Antarctica landscape
2019
International audience; The erosion history of Antarctica is fundamental to our understanding of interlinks between climate and glacier dynamics. However, because of the vast polar ice sheet covering more than 99% of Antarctica land mass, the continental surface response to glacial erosion remains largely unknown. Over the last decade the subglacial topography of Antarctica has been imaged by airborne radar surveys. These studies revealed high and complex sub-glacial relief in the core of the East Antarctic shield, interpreted as resulting from rifting episodes and low long-term erosion rates, or repeated large-scale glacial retreats and advances. In East Antarctica, thermochronology studie…
Pressure-temperature evolution during two granulite-facies metamorphic events (2.62 and 2.02 Ga) in rocks from the Central Zone of the Limpopo Belt, …
2018
Abstract The Central Zone of the Limpopo Belt in southern Africa is a classical example of a polymetamorphic terrane that experienced three metamorphic events at 3.22 Ga (M1), 2.66–2.61 Ga (M2) and 2.02 (M3). However, the geodynamic significance of these events is controversial as their P-T evolution was poorly constrained. We present new petrological and geochronological data for the M2 and M3 events. The Neoarchean M2 event is well-preserved in samples from a newly discovered enclave of supracrustal and magmatic rocks in the 2.612 Ga Bulai pluton that shielded the enclave against a Paleoproterozoic M3 overprint, which is dominant in rocks exposed outside the pluton. P-T pseudosection mode…
The relationship between eruptive activity, flank collapse, and sea level at volcanic islands: A long-term (>1 Ma) record offshore Montserrat, Les…
2016
Hole U1395B, drilled southeast of Montserrat during Integrated Ocean Drilling Program Expedition 340, provides a long (>1 Ma) and detailed record of eruptive and mass-wasting events (>130 discrete events). This record can be used to explore the temporal evolution in volcanic activity and landslides at an arc volcano. Analysis of tephra fall and volcaniclastic turbidite deposits in the drill cores reveals three heightened periods of volcanic activity on the island of Montserrat (∼930 to ∼900 ka, ∼810 to ∼760 ka, and ∼190 to ∼120 ka) that coincide with periods of increased volcano instability and mass-wasting. The youngest of these periods marks the peak in activity at the Soufriere Hills vol…
Advances in Fourier transform infrared spectroscopy of natural glasses: From sample preparation to data analysis
2014
Fourier transform infrared spectroscopy (FTIR) is an analytical technique utilized to measure the concentrations of H and C species in volcanic glasses. Water and CO2 are the most abundant volatile species in volcanic systems. Water is present in magmas in higher concentrations than CO2 and is also more soluble at lower pressures, and, therefore it is the dominant volatile forming bubbles during volcanic eruptions. Dissolved water affects both phase equilibria and melt physical properties such as density and viscosity, therefore, water is important for understanding magmatic processes. Additionally, quantitative measurements of different volatile species using FTIR can be achieved at high s…